Matches in SemOpenAlex for { <https://semopenalex.org/work/W2093040512> ?p ?o ?g. }
- W2093040512 endingPage "4043" @default.
- W2093040512 startingPage "4037" @default.
- W2093040512 abstract "Abstract Thioxanthone‐based 9‐(2‐Morpholine‐4yl‐acetyl)‐5‐thia‐napthasen‐12‐one (TX‐MPM) was synthesized and characterized as a one‐component novel visible photoinitiator. Its capability to act as an initiator for the polymerization of methyl methacrylate (MMA) was examined in photoreactor and also daylight. Photophysical properties: fluorescence and phosphorescence emission spectra and fluorescence quantum yield of TX‐MPM (ϕ f = 0.29) were determined. The phosphorescence lifetime was found 131 ms for TX‐MPM and 110 ms for initiator‐attached polymer (PMMA) at 77 K, indicated a π→π* nature of the lowest triplet state. A model compound, morpholino acetonapthone was used as quencher for the triplet states of TX‐MPM and the quenching rate constant was determined ( k q = 1.26 × 10 9 M −1 s −1 ). According to laser flash photolysis studies, intermolecular hydrogen abstraction process was more dominant path to the formation of the initiating radicals. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011" @default.
- W2093040512 created "2016-06-24" @default.
- W2093040512 creator A5000228604 @default.
- W2093040512 creator A5038297872 @default.
- W2093040512 creator A5078476547 @default.
- W2093040512 date "2011-07-18" @default.
- W2093040512 modified "2023-10-18" @default.
- W2093040512 title "A thioxanthone-based visible photoinitiator" @default.
- W2093040512 cites W1534618674 @default.
- W2093040512 cites W1964240606 @default.
- W2093040512 cites W1964364282 @default.
- W2093040512 cites W1967299634 @default.
- W2093040512 cites W1973812684 @default.
- W2093040512 cites W1980544202 @default.
- W2093040512 cites W1985767904 @default.
- W2093040512 cites W1988891100 @default.
- W2093040512 cites W1997847829 @default.
- W2093040512 cites W1998998572 @default.
- W2093040512 cites W2005723149 @default.
- W2093040512 cites W2007676734 @default.
- W2093040512 cites W2012829364 @default.
- W2093040512 cites W2012927223 @default.
- W2093040512 cites W2014603223 @default.
- W2093040512 cites W2015488087 @default.
- W2093040512 cites W2030640472 @default.
- W2093040512 cites W2034955165 @default.
- W2093040512 cites W2038368974 @default.
- W2093040512 cites W2040247057 @default.
- W2093040512 cites W2059352658 @default.
- W2093040512 cites W2064512984 @default.
- W2093040512 cites W2068630951 @default.
- W2093040512 cites W2070672422 @default.
- W2093040512 cites W2072065110 @default.
- W2093040512 cites W2082460367 @default.
- W2093040512 cites W2083077456 @default.
- W2093040512 cites W2087689999 @default.
- W2093040512 cites W2090631074 @default.
- W2093040512 cites W2091810494 @default.
- W2093040512 cites W2106677418 @default.
- W2093040512 cites W2108849304 @default.
- W2093040512 cites W2115035397 @default.
- W2093040512 cites W2124533006 @default.
- W2093040512 cites W2127282671 @default.
- W2093040512 cites W2143710710 @default.
- W2093040512 cites W2161167654 @default.
- W2093040512 cites W2172177651 @default.
- W2093040512 cites W3004479847 @default.
- W2093040512 doi "https://doi.org/10.1002/pola.24846" @default.
- W2093040512 hasPublicationYear "2011" @default.
- W2093040512 type Work @default.
- W2093040512 sameAs 2093040512 @default.
- W2093040512 citedByCount "48" @default.
- W2093040512 countsByYear W20930405122012 @default.
- W2093040512 countsByYear W20930405122013 @default.
- W2093040512 countsByYear W20930405122014 @default.
- W2093040512 countsByYear W20930405122015 @default.
- W2093040512 countsByYear W20930405122016 @default.
- W2093040512 countsByYear W20930405122017 @default.
- W2093040512 countsByYear W20930405122018 @default.
- W2093040512 countsByYear W20930405122019 @default.
- W2093040512 countsByYear W20930405122020 @default.
- W2093040512 countsByYear W20930405122021 @default.
- W2093040512 countsByYear W20930405122022 @default.
- W2093040512 countsByYear W20930405122023 @default.
- W2093040512 crossrefType "journal-article" @default.
- W2093040512 hasAuthorship W2093040512A5000228604 @default.
- W2093040512 hasAuthorship W2093040512A5038297872 @default.
- W2093040512 hasAuthorship W2093040512A5078476547 @default.
- W2093040512 hasConcept C111998727 @default.
- W2093040512 hasConcept C121332964 @default.
- W2093040512 hasConcept C121745418 @default.
- W2093040512 hasConcept C13472781 @default.
- W2093040512 hasConcept C139066938 @default.
- W2093040512 hasConcept C148898269 @default.
- W2093040512 hasConcept C15487406 @default.
- W2093040512 hasConcept C166940927 @default.
- W2093040512 hasConcept C171001562 @default.
- W2093040512 hasConcept C178790620 @default.
- W2093040512 hasConcept C181817918 @default.
- W2093040512 hasConcept C185592680 @default.
- W2093040512 hasConcept C188027245 @default.
- W2093040512 hasConcept C2777935641 @default.
- W2093040512 hasConcept C2778189152 @default.
- W2093040512 hasConcept C2780634384 @default.
- W2093040512 hasConcept C32909587 @default.
- W2093040512 hasConcept C44228677 @default.
- W2093040512 hasConcept C521977710 @default.
- W2093040512 hasConcept C62520636 @default.
- W2093040512 hasConcept C75473681 @default.
- W2093040512 hasConcept C76766466 @default.
- W2093040512 hasConcept C81022585 @default.
- W2093040512 hasConcept C91881484 @default.
- W2093040512 hasConcept C93391505 @default.
- W2093040512 hasConceptScore W2093040512C111998727 @default.
- W2093040512 hasConceptScore W2093040512C121332964 @default.
- W2093040512 hasConceptScore W2093040512C121745418 @default.
- W2093040512 hasConceptScore W2093040512C13472781 @default.
- W2093040512 hasConceptScore W2093040512C139066938 @default.