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- W2093044963 abstract "The cristobalitelike forms of the ternary silica analogues BPO4 and BAsO4 were investigated at high pressure by x-ray diffraction and theoretical methods. The behavior of these compounds represents an extreme case in which the tilt angle of the constituent tetrahedra increases in a spectacular way at high pressure resulting in a major change in topology from a cristobalitelike framework towards a collapsed cristobalite structure. These compounds provide the first examples of the collapse of a framework structure to a close-packed form in a continuous manner without an intervening phase transition." @default.
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- W2093044963 date "2003-07-03" @default.
- W2093044963 modified "2023-10-18" @default.
- W2093044963 title "Collapsing Cristobalitelike Structures in Silica Analogues at High Pressure" @default.
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- W2093044963 doi "https://doi.org/10.1103/physrevlett.91.015503" @default.
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