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- W2093081449 abstract "The title compounds, [Li(C 14 H 20 O 5 )(H 2 O)] 2 [Cu 4 I 6 ].2C 14 H 20 O 5 , [Cs(C 14 H 20 O 5 ) 2 ] 2 [Cu 4 I 6 ] and [Na 2 (C 12 H 24 O 6 ) 2 (H 2 O) 3 ][Cu 4 I 6 ], respectively, all show similar [Cu 4 I 6 ] 2- clusters disordered about a center of symmetry. The Cu atoms are three-coordinate, with an average Cu-I distance of 2.596 (3) A. Alkali-bound crown-ether groups serve as counter-ions. The three solid materials display identical emission in the visible when excited in the ultraviolet. Calculations of the atomic contributions to frontier orbitals show the highest occupied molecular orbital (HOMO) to be based primarily on contributions from four of the six I atoms and the lowest unoccupied molecular orbital (LUMO) to be primarily copper-based and involving contributions from the four Cu atoms." @default.
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- W2093081449 date "1999-09-15" @default.
- W2093081449 modified "2023-10-11" @default.
- W2093081449 title "Aqua(benzo-15-crown-5)lithium–hexa-μ-iodotetracopper–benzo-15-crown-5 (2/1/2), bis[bis(benzo-15-crown-5)caesium] hexa-μ-iodotetracopper and μ-aqua-bis[aqua(18-crown-6)sodium] hexa-μ-iodotetracopper" @default.
- W2093081449 doi "https://doi.org/10.1107/s0108270199007040" @default.
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