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- W2093083313 abstract "The pit initiation mechanism for a passive metal is considered on the assumption that pits nucleate through two-step processes. First, local fluctuation of the ionic concentration and of the electric field occur in the solution, so halide ions accumulate at anodic sites on the passive film. This starts a secondary process, where hemispherical nuclei are formed and grow into the film, which breaks down the film and initiates pits. The scope for these processes is discussed separately by the stability criteria based on the dynamic and the irreversible thermodynamic stability theories. The model is further tested for the occurrence of “noise phenomenon” in relation to the “birth and death” stochastic approach." @default.
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- W2093083313 date "1990-01-01" @default.
- W2093083313 modified "2023-09-24" @default.
- W2093083313 title "A two-step initiation hypothesis of pitting corrosion in passive metals" @default.
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- W2093083313 doi "https://doi.org/10.1016/0010-938x(90)90145-u" @default.
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