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- W2093087029 abstract "Oxidation with ruthenium tetroxide of alicyclic N-methylamines, such as nicotine (1), trans-phendi-metrazine (2), tropacocaine (3) and pempidine (4), leads to the N-demethylated, N-formyl and, where possible, lactam derivatives. Only from pempidine the N-oxide was obtained. All products obtained by this procedure are metabolites of compounds 1, 2, 3 and 4. Chemische Studien zum Arzneimittelmetabolismus: Oxidation einiger N-methylierter alicyclischer medizinisch verwendeter Amine mit Rutheniumtetroxid Die Oxidation einiger N-methylierter alicyclischer Amine mit Rutheniumtetroxid, wie Nicotin (1), trans-Phendimetrazin (2), Tropacocain (3) und Pempidin (4), ergaben die entsprechenden N-demethylierten, N-Formyl- und, soweit möglich, Lactamderivate. Nur bei der Oxidation von Pempidin wurde das N-Oxid erhalten. Alle bei diesem Oxidationsverfahren erhaltenen Verbindungen sind in vivo Metabolite der Verbindungen 1, 2, 3 und 4." @default.
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- W2093087029 date "1984-01-01" @default.
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- W2093087029 title "Chemical Studies on Drug Metabolism: Oxidation with Ruthenium Tetroxide of Some Medicinal AlicyclicN-Methylamines" @default.
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- W2093087029 doi "https://doi.org/10.1002/ardp.19843170106" @default.
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