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- W2093127941 abstract "Publisher Summary This chapter describes the organometallic aspects of tris(pyrazolylborate) anion (Tp) chemistry of the group 8 metals—that is, the synthesis, reactivity, and reaction mechanisms of the metal–carbon bond and other organic and inorganic functionalities present in the molecule; organometallic reagents in organic, inorganic, and polymer synthesis; and catalytic processes in which an organometallic compound is the precatalyst or catalyst or in which organometallic species are intermediates. Tp and its derivatives, such as Tp*(hydridotris(3,5 dimethylpyrazolyl)borate) and pzTp (tetrapyrazolylborate), have found increasing applications in all areas of chemistry with most of the transition metals. Tp is often compared with Cp (cyclopentadienyl) and Cp* (the pentamethyl derivative) due to the same charge and number of electrons donated (anionic 6e donors) as well as the facial geometry typically adopted. The cone angle of parent Tp close to 180 o is well above the 100 o and 146 o calculated for Cp and Cp*, respectively. In contrast, the organometallic chemistry of group 8 poly(pyrazole)borates is slow to emerge and still remains comparatively unexplored in the case of iron and osmium. Although higher oxidation state chemistry is also beginning to emerge, at present this is more advanced for osmium than the lighter elements." @default.
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- W2093127941 date "2008-07-29" @default.
- W2093127941 modified "2023-09-26" @default.
- W2093127941 title "ChemInform Abstract: The Organometallic Chemistry of Group 8 Tris(pyrazolyl)borate Complexes" @default.
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- W2093127941 doi "https://doi.org/10.1002/chin.200831232" @default.
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