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- W2093135430 abstract "Formation enthalpies ΔHv of single vacancies in all AIBIIIC2VI chalcopyrite structure compounds are estimated using the macroscopic cavity model. A comparison with atomic sublimation enthalpies ΔHsub of the BIII and CVI atoms derived from existing partial vapour pressure data shows that within the accuracy of this data and the theoretical calculations the relation ΔHv ⪆ ΔHsub is fulfilled as expected from general considerations. Bildungsenthalpien ΔHv für Einzelvakanzen sind für alle AIBIIIC2VI-Verbindungen mit Chalkopyritstruktur unter Verwendung des makroskopischen Hohlraummodells abgeschätzt worden. Ein Vergleich mit aus existierenden Partialdampfdruckdaten abgeleiteten atomaren Sublimationsenthalpien ΔHsub der BIII- und CVI-Atome zeigt, daß die auf Grund allgemeiner Überlegungen zu erwartende Beziehung ΔHv ⪆ ΔHsub innerhalb der Genauigkeit dieser Daten und der theoretischen Rechnungen erfüllt ist." @default.
- W2093135430 created "2016-06-24" @default.
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- W2093135430 date "1983-01-01" @default.
- W2093135430 modified "2023-10-13" @default.
- W2093135430 title "Vacancy formation enthalpies in AIBIIIC2VI chalcopyrite semiconductors" @default.
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- W2093135430 doi "https://doi.org/10.1002/crat.2170180710" @default.
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