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- W2093141033 abstract "A new reaction route of methanol synthesis at low temperature from CO2-containing syngas with Cu/ZnO catalyst and the aid of alcohols has been developed in a batch and a flow-type semi-batch reactors. The use of alcohols as catalytic solvents realized methanol synthesis at 443 K with formate as an intermediate. The activity of methanol synthesis depends on types and structures of alcohols. Among all alcohols, 2-alcohol exhibited the highest activity. With the aid of 2-butanol, the one-pass 47.0% conversion and 98.9% selectivity were achieved at a mild condition, 443 K and 50 bar. The new reaction route of methanol synthesis is a practical method for near future technology." @default.
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- W2093141033 date "2004-06-01" @default.
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- W2093141033 title "Development of a new low-temperature methanol synthesis process" @default.
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- W2093141033 doi "https://doi.org/10.1016/j.cattod.2004.01.006" @default.
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