FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2093143130> ?p ?o ?g. }

• W2093143130 endingPage "356" @default.
• W2093143130 startingPage "347" @default.
• W2093143130 abstract "Reaction of VO(acac)(2) with 2-mercaptophenol (mpH(2)) in the presence of triethylamine gives the mononuclear tris complex (Et(3)NH)(2)[V(mp)(3)] (1), in which the vanadyl oxygen has been displaced. An analogous reaction using 2-mercapto-4-methylphenol (mmpH(2)) afforded (Et(3)NH)(PNP)[V(mmp)(3)] (2), which was structurally characterized. 2 crystallizes in the orthorhombic space group Pna2(1 )with unit cell parameters (at -163 degrees C) a = 23.974(7) Å, b = 9.569(4) Å, c = 25.101(6) Å, and Z = 4. The coordination geometry around the vanadium is between octahedral and trigonal prismatic. Reaction of VO(acac)(2 )with the sodium salt of 2-mercaptophenol produces the vanadyl(IV) complex Na(Ph(4)P)[VO(mp)(2)].Et(2)O (3), which crystallizes in the triclinic space group P&onemacr; with unit cell parameters (at -135 degrees C) a = 12.185(4) Å, b = 12.658(4) Å, c = 14.244(4) Å, alpha = 103.19(2) degrees, beta = 100.84(2) degrees, and gamma = 114.17(2) degrees. The unit cell of 3 contains a pair of symmetry-related [VO(mp)(2)](2)(-) units bridged through vanadyl and ligand oxygen atoms by a pair of sodium ions, in addition to two PPh(4)(+) ions. The coordination geometry around the vanadium is square pyramidal, with a V=O bond length of 1.611(5) Å. 1, 2, and 3 are characterized by IR and UV-vis spectroscopies, magnetic susceptibility, EPR spectroscopy, and cyclic voltammetry. 1 and 2 can be oxidized by I(2, )Cp(2)Fe(+), or O(2) to [V(mp)(3)](-) and [V(mmp)(3)](-), respectively, which in turn can be reduced back to the dianions by oxalate ion. These reversible redox processes can be followed by UV-vis spectroscopy." @default.
• W2093143130 created "2016-06-24" @default.
• W2093143130 creator A5013009581 @default.
• W2093143130 creator A5029118275 @default.
• W2093143130 creator A5035121790 @default.
• W2093143130 creator A5042755945 @default.
• W2093143130 creator A5044539076 @default.
• W2093143130 date "1996-01-01" @default.
• W2093143130 modified "2023-10-18" @default.
• W2093143130 title "Vanadium(IV) Complexes with Mixed O,S Donor Ligands. Syntheses, Structures, and Properties of the Anions Tris(2-mercapto-4-methylphenolato)vanadate(IV) and Bis(2-mercaptophenolato)oxovanadate(IV)" @default.
• W2093143130 cites W135647501 @default.
• W2093143130 cites W1570541170 @default.
• W2093143130 cites W1965299549 @default.
• W2093143130 cites W1965456641 @default.
• W2093143130 cites W1970664190 @default.
• W2093143130 cites W1972945802 @default.
• W2093143130 cites W1978904227 @default.
• W2093143130 cites W1980377213 @default.
• W2093143130 cites W1986804029 @default.
• W2093143130 cites W1987372363 @default.
• W2093143130 cites W1989272126 @default.
• W2093143130 cites W2002576040 @default.
• W2093143130 cites W2006573984 @default.
• W2093143130 cites W2008423370 @default.
• W2093143130 cites W2010298984 @default.
• W2093143130 cites W2011743778 @default.
• W2093143130 cites W2012370569 @default.
• W2093143130 cites W2018016840 @default.
• W2093143130 cites W2020648685 @default.
• W2093143130 cites W2021423099 @default.
• W2093143130 cites W2031053165 @default.
• W2093143130 cites W2037659465 @default.
• W2093143130 cites W2039333963 @default.
• W2093143130 cites W2041549617 @default.
• W2093143130 cites W2042264900 @default.
• W2093143130 cites W2045115185 @default.
• W2093143130 cites W2055853756 @default.
• W2093143130 cites W2067049591 @default.
• W2093143130 cites W2074964110 @default.
• W2093143130 cites W2078107419 @default.
• W2093143130 cites W2080944859 @default.
• W2093143130 cites W2084188389 @default.
• W2093143130 cites W2086649882 @default.
• W2093143130 cites W2087438947 @default.
• W2093143130 cites W2090864912 @default.
• W2093143130 cites W2135945740 @default.
• W2093143130 cites W214451653 @default.
• W2093143130 cites W2314703124 @default.
• W2093143130 cites W2316536362 @default.
• W2093143130 cites W2949525632 @default.
• W2093143130 cites W2952027434 @default.
• W2093143130 cites W2952657550 @default.
• W2093143130 cites W3136702113 @default.
• W2093143130 cites W3137276436 @default.
• W2093143130 cites W3137552403 @default.
• W2093143130 cites W3139445897 @default.
• W2093143130 cites W4249257424 @default.
• W2093143130 doi "https://doi.org/10.1021/ic950792b" @default.
• W2093143130 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11666215" @default.
• W2093143130 hasPublicationYear "1996" @default.
• W2093143130 type Work @default.
• W2093143130 sameAs 2093143130 @default.
• W2093143130 citedByCount "70" @default.
• W2093143130 countsByYear W20931431302012 @default.
• W2093143130 countsByYear W20931431302013 @default.
• W2093143130 countsByYear W20931431302015 @default.
• W2093143130 countsByYear W20931431302016 @default.
• W2093143130 countsByYear W20931431302017 @default.
• W2093143130 countsByYear W20931431302018 @default.
• W2093143130 countsByYear W20931431302020 @default.
• W2093143130 countsByYear W20931431302021 @default.
• W2093143130 countsByYear W20931431302022 @default.
• W2093143130 countsByYear W20931431302023 @default.
• W2093143130 crossrefType "journal-article" @default.
• W2093143130 hasAuthorship W2093143130A5013009581 @default.
• W2093143130 hasAuthorship W2093143130A5029118275 @default.
• W2093143130 hasAuthorship W2093143130A5035121790 @default.
• W2093143130 hasAuthorship W2093143130A5042755945 @default.
• W2093143130 hasAuthorship W2093143130A5044539076 @default.
• W2093143130 hasConcept C112887158 @default.
• W2093143130 hasConcept C115624301 @default.
• W2093143130 hasConcept C116569031 @default.
• W2093143130 hasConcept C121332964 @default.
• W2093143130 hasConcept C155860418 @default.
• W2093143130 hasConcept C170493617 @default.
• W2093143130 hasConcept C178790620 @default.
• W2093143130 hasConcept C179104552 @default.
• W2093143130 hasConcept C185592680 @default.
• W2093143130 hasConcept C187961010 @default.
• W2093143130 hasConcept C194196696 @default.
• W2093143130 hasConcept C198819137 @default.
• W2093143130 hasConcept C2781116636 @default.
• W2093143130 hasConcept C32909587 @default.
• W2093143130 hasConcept C37243968 @default.
• W2093143130 hasConcept C42228675 @default.
• W2093143130 hasConcept C46141821 @default.
• W2093143130 hasConcept C504678139 @default.
• W2093143130 hasConcept C55493867 @default.

• next