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- W2093152068 abstract "At elevated temperatures, the aluminum complex [(dpp-BIAN)AlI(Et2O)] (1) splits the C-O bonds of diethyl ether and tetrahydrofurane yielding the dimeric alkoxides [(dpp-BIAN)AlOEt]2 (2) and [(dpp-BIAN)AlO(CH2)4I]2 (3), respectively. Already at ambient temperatures, a cleavage of the C-O bond of THF is to observe in the reaction of 1 with CpNa in THF as confirmed by the formation of [(dpp-BIAN)AlO(CH2)4C5H5]2 (4a) and [(dpp-BIAN)Al{O(CH2)4C5H5}(THF)] (4b) in a molar ratio of 1:2. The reaction of 1 with t-BuOK affords the monomeric alkoxide [(dpp-BIAN)AlO-t-Bu(Et2O)] (5). Compounds 2, 3, and 4a/b were characterized by elemental analyses and IR spectra. Additionally, the structures of 2 and 3 were determined by single crystal X-ray diffraction." @default.
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- W2093152068 date "2008-02-01" @default.
- W2093152068 modified "2023-10-07" @default.
- W2093152068 title "C-O Bond Cleavage of Diethyl Ether and Tetrahydrofurane by [(dpp-BIAN)AlI(Et2O)] [dpp-BIAN = 1,2-bis[(2,6-di-iso-propylphenyl)-imino]acenaphthene]" @default.
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- W2093152068 doi "https://doi.org/10.1002/zaac.200700411" @default.
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