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- W2093157076 abstract "Abstract Radioactive [ 3 H]5-demethoxyubiquinone-9 (3-methyl-2-nonaprenyl-6-methoxy-1,4-benzo-quione), an intermediate in the biosynthesis of ubiquione-9 by selected microorganisms and by the rat, has been synthesized. 4-Methyl-3-nitrophenol was converted to the corresponding anisole with [ 3 H]methyl iodide and the anisole was then reduced to the corresponding aniline. Oxidation of 6-methyl-3-methoxy [ 3 H]aniline with chromic acid gave the corresponding 1,4-benzo-quinone which was reduced and alkylated with solanesol in the presence of boron trifluorideetherate. Oxidation with ferric chloride gave two isomers, 5-demethoxyubiquinone-9 and 6-methyl-2-nonaprenyl-3-methoxy-1,4-benzoquinone which were separated by thin layer chromatography. The [ 3 H]methoxyl-5-demethoxyubiquinone-9 prepared had a specific radioactivity of 100 mCi/mmole." @default.
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- W2093157076 date "1974-10-01" @default.
- W2093157076 modified "2023-09-27" @default.
- W2093157076 title "Synthesis and stability of [3H] 5—demethoxyubiquinone-9" @default.
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- W2093157076 doi "https://doi.org/10.1016/0009-3084(74)90027-9" @default.
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