Matches in SemOpenAlex for { <https://semopenalex.org/work/W2093166039> ?p ?o ?g. }
- W2093166039 endingPage "18814" @default.
- W2093166039 startingPage "18804" @default.
- W2093166039 abstract "Using (semi-)grand canonical Monte Carlo simulations of a polyelectrolyte chain of length N where the charges are in contact with a reservoir of constant chemical potential μ given by the solution pH, we study the behavior of annealed polyelectrolytes in a poor solvent. We focus on the conformational properties in the close-to-ϑ-point regime τ < τ* ∼ N-1/5u-3/5, which can be reached either by reducing electrostatic interaction strength u = λB/b or by improving solvent quality, i.e., by reducing τ = (ϑ − T)/ϑ. We investigate the conformations with regard to parameters u, τ, and μ and explore in which conditions pearl-necklace-like structures are stable. Most of the pearl-necklace parameters are found to obey the scaling relations predicted for quenched polyelectrolytes. However, similarly to the behavior known for this class of polyelectrolytes, we obtain large fluctuations in pearl number and size. In agreement with theoretical predictions we find a nonuniform charge distribution between pearls and strings. For τ ≪ 1 and moderate interaction strength we demonstrate that a cascade of pearl-necklace transitions can be initiated by changing μ, i.e., by tuning the solution pH." @default.
- W2093166039 created "2016-06-24" @default.
- W2093166039 creator A5048197719 @default.
- W2093166039 creator A5071938291 @default.
- W2093166039 date "2004-11-13" @default.
- W2093166039 modified "2023-09-25" @default.
- W2093166039 title "Pearl-Necklace Structures in Annealed Polyelectrolytes" @default.
- W2093166039 cites W1553156680 @default.
- W2093166039 cites W1963714100 @default.
- W2093166039 cites W1968261748 @default.
- W2093166039 cites W1968399523 @default.
- W2093166039 cites W1975980274 @default.
- W2093166039 cites W1978114285 @default.
- W2093166039 cites W1994877908 @default.
- W2093166039 cites W1999385288 @default.
- W2093166039 cites W2000702026 @default.
- W2093166039 cites W2013769305 @default.
- W2093166039 cites W2014860771 @default.
- W2093166039 cites W2017002150 @default.
- W2093166039 cites W2027512599 @default.
- W2093166039 cites W2029065404 @default.
- W2093166039 cites W2034618493 @default.
- W2093166039 cites W2036458085 @default.
- W2093166039 cites W2037602332 @default.
- W2093166039 cites W2040714008 @default.
- W2093166039 cites W2040855023 @default.
- W2093166039 cites W2041036042 @default.
- W2093166039 cites W2041990673 @default.
- W2093166039 cites W2044290254 @default.
- W2093166039 cites W2044751768 @default.
- W2093166039 cites W2045540157 @default.
- W2093166039 cites W2051780494 @default.
- W2093166039 cites W2051995948 @default.
- W2093166039 cites W2056943601 @default.
- W2093166039 cites W2068951467 @default.
- W2093166039 cites W2069850099 @default.
- W2093166039 cites W2073905044 @default.
- W2093166039 cites W2076798177 @default.
- W2093166039 cites W2082847465 @default.
- W2093166039 cites W2085409823 @default.
- W2093166039 cites W2086033068 @default.
- W2093166039 cites W2146585930 @default.
- W2093166039 cites W2159444948 @default.
- W2093166039 cites W3022334511 @default.
- W2093166039 doi "https://doi.org/10.1021/jp0464270" @default.
- W2093166039 hasPublicationYear "2004" @default.
- W2093166039 type Work @default.
- W2093166039 sameAs 2093166039 @default.
- W2093166039 citedByCount "47" @default.
- W2093166039 countsByYear W20931660392012 @default.
- W2093166039 countsByYear W20931660392014 @default.
- W2093166039 countsByYear W20931660392015 @default.
- W2093166039 countsByYear W20931660392016 @default.
- W2093166039 countsByYear W20931660392017 @default.
- W2093166039 countsByYear W20931660392018 @default.
- W2093166039 countsByYear W20931660392019 @default.
- W2093166039 countsByYear W20931660392020 @default.
- W2093166039 countsByYear W20931660392021 @default.
- W2093166039 countsByYear W20931660392022 @default.
- W2093166039 countsByYear W20931660392023 @default.
- W2093166039 crossrefType "journal-article" @default.
- W2093166039 hasAuthorship W2093166039A5048197719 @default.
- W2093166039 hasAuthorship W2093166039A5071938291 @default.
- W2093166039 hasConcept C114614502 @default.
- W2093166039 hasConcept C117626034 @default.
- W2093166039 hasConcept C138885662 @default.
- W2093166039 hasConcept C147789679 @default.
- W2093166039 hasConcept C153356533 @default.
- W2093166039 hasConcept C159467904 @default.
- W2093166039 hasConcept C178790620 @default.
- W2093166039 hasConcept C185592680 @default.
- W2093166039 hasConcept C192562407 @default.
- W2093166039 hasConcept C2524010 @default.
- W2093166039 hasConcept C27206212 @default.
- W2093166039 hasConcept C2779251273 @default.
- W2093166039 hasConcept C2779511736 @default.
- W2093166039 hasConcept C33923547 @default.
- W2093166039 hasConcept C521977710 @default.
- W2093166039 hasConcept C99844830 @default.
- W2093166039 hasConceptScore W2093166039C114614502 @default.
- W2093166039 hasConceptScore W2093166039C117626034 @default.
- W2093166039 hasConceptScore W2093166039C138885662 @default.
- W2093166039 hasConceptScore W2093166039C147789679 @default.
- W2093166039 hasConceptScore W2093166039C153356533 @default.
- W2093166039 hasConceptScore W2093166039C159467904 @default.
- W2093166039 hasConceptScore W2093166039C178790620 @default.
- W2093166039 hasConceptScore W2093166039C185592680 @default.
- W2093166039 hasConceptScore W2093166039C192562407 @default.
- W2093166039 hasConceptScore W2093166039C2524010 @default.
- W2093166039 hasConceptScore W2093166039C27206212 @default.
- W2093166039 hasConceptScore W2093166039C2779251273 @default.
- W2093166039 hasConceptScore W2093166039C2779511736 @default.
- W2093166039 hasConceptScore W2093166039C33923547 @default.
- W2093166039 hasConceptScore W2093166039C521977710 @default.
- W2093166039 hasConceptScore W2093166039C99844830 @default.
- W2093166039 hasIssue "49" @default.
- W2093166039 hasLocation W20931660391 @default.
- W2093166039 hasOpenAccess W2093166039 @default.