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• W2093192007 abstract "4,4′-bis(dimethylamino)-benzophenone (1) is shown to self-assemble in the solid phase with 1,4-diiodo-tetrafluoro-benzene (TFDIB) to form the air stable compound 1 TFDIB. Single crystal X-ray analysis of this compound reveals a structure consisting of ribbon-like polymeric chains of alternating donor and acceptor molecules. The directing non-covalent halogen bond is characterised by a relatively long O⋯I distance of 3.097 Å and an O⋯I–C angle of 163.29°. These bond characteristics are due to the coordination of each carbonyl oxygen with two iodine atoms, resulting in a ‘zigzag’ geometry of the chains. Carbonyl derivatives can thus be considered as new tectons for the formation of hybrid perfluorocarbon–hydrocarbon crystalline materials." @default.
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• W2093192007 date "2005-03-01" @default.
• W2093192007 modified "2023-10-18" @default.
• W2093192007 title "First molecular self-assembly of 1,4-diiodo-tetrafluoro-benzene and a ketone via (O⋯I) non-covalent halogen bonds" @default.
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• W2093192007 doi "https://doi.org/10.1016/j.molstruc.2004.10.008" @default.
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