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- W2093205518 abstract "A new layered iron oxide, Pb1-xSr4Fe2O9-δ, has been isolated for 0 ≤ x ≤ 0.2. Its structural model which corresponds to a regular intergrowth of single [SrFeO3-δ]∞ perovskite layers with single [SrO]∞ and double [(SrO)(Pb1-xO)]∞ rock salt layers, has been established by high resolution electron microscopy (HREM) and powder XRD. The existence of numerous defects—local variation of the nature of the cations, modulations of the atomic layers, and intergrowth defects interpreted as [Sr3Fe2O7-δ]∞ and [Sr4Fe3O10-δ] layers—has been observed by HREM. The existence for Fe(III) of two 5 + 1 coordinations for x = 0, and of three coordinations for x ≠ 0 (two 5 + 1 and one pure pyramidal coordination) has been deduced from Mössbauer spectroscopy measurements." @default.
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- W2093205518 date "1993-01-01" @default.
- W2093205518 modified "2023-10-18" @default.
- W2093205518 title "Pb1-xSr4Fe2O9-δ: A Layered Iron Oxide Intergrowth of 1201- and 0201- Type Structures" @default.
- W2093205518 doi "https://doi.org/10.1006/jssc.1993.1004" @default.
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