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- W2093205817 abstract "We have studied the YBa2Cu3Ox compounds using the Fe Mössbauer effect as a function of hydrogen reduction. This technique does not alter the orthorhombic crystal structure of the compound for short reduction times. On the other hand, oxygen is removed and the Tc of the sample is reduced in the process. The Mössbauer effect measurements show that oxygen leaves five-fold coordinated Cu (1) sites and creates planar oxygen coordinated sites. Mössbauer measurements in the insulating 1-2-3 phase show that there are only four and six-fold oxygen coordinations around the Cu (1) site. Some impurity phases have been created in the initial fabrication process and the Mössbauer effect shows that these impurity phases could transform to magnetic phases during the reduction process." @default.
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- W2093205817 date "1991-05-01" @default.
- W2093205817 modified "2023-10-14" @default.
- W2093205817 title "Oxygen removal by hydrogen gas in 57Fe doped YBa2Cu3Ox" @default.
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- W2093205817 doi "https://doi.org/10.1016/0038-1098(91)90689-s" @default.
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