FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2093208511> ?p ?o ?g. }

• W2093208511 endingPage "13538" @default.
• W2093208511 startingPage "13531" @default.
• W2093208511 abstract "The absolute rate coefficients for the hydrogen abstraction reactions from CH3CCl3 (k1), CH3CCl2F (k2), and CH3CClF2 (k3) by chlorine atoms in gas phase have been measured as a function of temperature using the discharge flow/mass spectrometric technique (DF/MS). The reactions were investigated under pseudo-first-order conditions with Cl atoms in large excess with respect to the haloethanes. The temperature dependence of the rate coefficients is expressed in the Arrhenius form: k1(298−416K) = (2. ) ×10-12 exp[−(1790 ± 320)/T], k2(299−429K) = (3. ) × 10-12 exp[−(2220 ± 150)/T], k3(298−438K) = (1. ) × 10-12 exp[−(2420 ± 400)/T]. The units of the rate constants are cm3 molecule-1 s-1, and the quoted uncertainties are ±2σ. For understanding the reaction path mechanism of the chlorination of the studied halogen-substituted ethanes, ab initio molecular orbital calculations were performed. Transition state structures were determined. These calculations lead to predictions of preexponential factors in the same order of magnitude of measured values. The ab initio energetics of the reactions were corrected using the ISO-M method, a mixing of isodesmic reactions for obtaining reaction enthalpies and concept of intrinsic energy of Marcus to deduce activation energies. A reasonably good agreement with the experimental values were found." @default.
• W2093208511 created "2016-06-24" @default.
• W2093208511 creator A5009153352 @default.
• W2093208511 creator A5021566169 @default.
• W2093208511 creator A5052224997 @default.
• W2093208511 creator A5053796689 @default.
• W2093208511 creator A5059797745 @default.
• W2093208511 creator A5080150267 @default.
• W2093208511 creator A5080788131 @default.
• W2093208511 date "1996-01-01" @default.
• W2093208511 modified "2023-10-07" @default.
• W2093208511 title "Rate Coefficients of the Reactions of Chlorine Atoms with Haloethanes of Type CH₃CCl₃_-<i>_x</i>F<i>_x</i> (<i>x</i> = 0, 1, and 2): Experimental and ab Initio Theoretical Studies" @default.
• W2093208511 cites W1700599447 @default.
• W2093208511 cites W1963688013 @default.
• W2093208511 cites W1970096506 @default.
• W2093208511 cites W1972347830 @default.
• W2093208511 cites W1991782975 @default.
• W2093208511 cites W1998931710 @default.
• W2093208511 cites W2013899332 @default.
• W2093208511 cites W2018794409 @default.
• W2093208511 cites W2019479497 @default.
• W2093208511 cites W2019538235 @default.
• W2093208511 cites W2032139678 @default.
• W2093208511 cites W2037218890 @default.
• W2093208511 cites W2043816663 @default.
• W2093208511 cites W2047269263 @default.
• W2093208511 cites W2049336078 @default.
• W2093208511 cites W2049757378 @default.
• W2093208511 cites W2054230964 @default.
• W2093208511 cites W2061138749 @default.
• W2093208511 cites W2063813659 @default.
• W2093208511 cites W2067557952 @default.
• W2093208511 cites W2068077887 @default.
• W2093208511 cites W2094349167 @default.
• W2093208511 cites W2094642658 @default.
• W2093208511 cites W2095551568 @default.
• W2093208511 cites W2314198188 @default.
• W2093208511 cites W285629475 @default.
• W2093208511 cites W2949776625 @default.
• W2093208511 cites W3083311034 @default.
• W2093208511 cites W4251299242 @default.
• W2093208511 doi "https://doi.org/10.1021/jp9603243" @default.
• W2093208511 hasPublicationYear "1996" @default.
• W2093208511 type Work @default.
• W2093208511 sameAs 2093208511 @default.
• W2093208511 citedByCount "48" @default.
• W2093208511 countsByYear W20932085112012 @default.
• W2093208511 countsByYear W20932085112013 @default.
• W2093208511 countsByYear W20932085112015 @default.
• W2093208511 countsByYear W20932085112017 @default.
• W2093208511 countsByYear W20932085112018 @default.
• W2093208511 countsByYear W20932085112019 @default.
• W2093208511 countsByYear W20932085112020 @default.
• W2093208511 crossrefType "journal-article" @default.
• W2093208511 hasAuthorship W2093208511A5009153352 @default.
• W2093208511 hasAuthorship W2093208511A5021566169 @default.
• W2093208511 hasAuthorship W2093208511A5052224997 @default.
• W2093208511 hasAuthorship W2093208511A5053796689 @default.
• W2093208511 hasAuthorship W2093208511A5059797745 @default.
• W2093208511 hasAuthorship W2093208511A5080150267 @default.
• W2093208511 hasAuthorship W2093208511A5080788131 @default.
• W2093208511 hasConcept C121332964 @default.
• W2093208511 hasConcept C144557053 @default.
• W2093208511 hasConcept C147368240 @default.
• W2093208511 hasConcept C147597530 @default.
• W2093208511 hasConcept C147789679 @default.
• W2093208511 hasConcept C148898269 @default.
• W2093208511 hasConcept C155647269 @default.
• W2093208511 hasConcept C178790620 @default.
• W2093208511 hasConcept C183971685 @default.
• W2093208511 hasConcept C185592680 @default.
• W2093208511 hasConcept C2780263894 @default.
• W2093208511 hasConcept C2781442258 @default.
• W2093208511 hasConcept C2993530813 @default.
• W2093208511 hasConcept C32909587 @default.
• W2093208511 hasConcept C46062151 @default.
• W2093208511 hasConcept C505241676 @default.
• W2093208511 hasConcept C512968161 @default.
• W2093208511 hasConcept C517835270 @default.
• W2093208511 hasConcept C62520636 @default.
• W2093208511 hasConcept C86183883 @default.
• W2093208511 hasConcept C93391505 @default.
• W2093208511 hasConcept C95121573 @default.
• W2093208511 hasConcept C97355855 @default.
• W2093208511 hasConceptScore W2093208511C121332964 @default.
• W2093208511 hasConceptScore W2093208511C144557053 @default.
• W2093208511 hasConceptScore W2093208511C147368240 @default.
• W2093208511 hasConceptScore W2093208511C147597530 @default.
• W2093208511 hasConceptScore W2093208511C147789679 @default.
• W2093208511 hasConceptScore W2093208511C148898269 @default.
• W2093208511 hasConceptScore W2093208511C155647269 @default.
• W2093208511 hasConceptScore W2093208511C178790620 @default.
• W2093208511 hasConceptScore W2093208511C183971685 @default.
• W2093208511 hasConceptScore W2093208511C185592680 @default.
• W2093208511 hasConceptScore W2093208511C2780263894 @default.
• W2093208511 hasConceptScore W2093208511C2781442258 @default.
• W2093208511 hasConceptScore W2093208511C2993530813 @default.
• W2093208511 hasConceptScore W2093208511C32909587 @default.

• next