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- W2093225327 abstract "Treatment of optically active 1-chlorovinyl p-tolyl sulfoxides having two different substituents at the 2-position, which were synthesized from aldehydes or unsymmetrical ketones and (R)-(−)-chloromethyl p-tolyl sulfoxide in two or three steps, with the lithium enolate of tert-butyl acetate gave optically active adducts in 99% chiral induction from the sulfur stereogenic center. The adducts were converted to optically active esters, carboxylic acids, and γ-lactones, which have a tertiary or a quaternary carbon stereogenic center at the β-position. A synthesis of optically active spiro-lactones was realized starting from 2-cyclohexenone by this method." @default.
- W2093225327 created "2016-06-24" @default.
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- W2093225327 date "2005-02-01" @default.
- W2093225327 modified "2023-10-09" @default.
- W2093225327 title "Asymmetric synthesis of both enantiomers of esters and γ-lactones from optically active 1-chlorovinyl p-tolyl sulfoxides and lithium ester enolates with the formation of a tertiary or a quaternary carbon stereogenic center at the β-position" @default.
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- W2093225327 doi "https://doi.org/10.1016/j.tetasy.2004.11.085" @default.
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