Matches in SemOpenAlex for { <https://semopenalex.org/work/W2093232270> ?p ?o ?g. }
- W2093232270 endingPage "21" @default.
- W2093232270 startingPage "1" @default.
- W2093232270 abstract "Diphenyl carbonate (DPC) is considered as a substitution for phosgene to synthesize polycarbonate resins. Conventional production of DPC involves reactions of phosgene and phenol. However, the phosgene process has drawbacks such as environmental and safety problems associated with using highly toxic phosgene as the reagent, which results in the formation of chlorine salts, and copious amounts of methylene chloride as the solvent. For these reasons, environmentally friendly processes for DPC production without using phosgene have been proposed and developed in the past decades. So far, the most promising alternatives appear to be the transesterification of dimethyl carbonate (DMC) and phenol, the direct oxidative carbonylation of phenol, and transesterification of dialkyl oxalates and phenol. This paper attempts to review recent literature concerning process design and catalytic chemistry for these phosgene-free approaches. The advantages and disadvantages are discussed for each reaction. Strategies to overcome potential problems are provided. The perspectives to improve catalytic efficiency of phosgene-free process are proposed." @default.
- W2093232270 created "2016-06-24" @default.
- W2093232270 creator A5043956105 @default.
- W2093232270 creator A5047030779 @default.
- W2093232270 creator A5071404237 @default.
- W2093232270 date "2007-01-02" @default.
- W2093232270 modified "2023-10-14" @default.
- W2093232270 title "Phosgene-free approaches to catalytic synthesis of diphenyl carbonate and its intermediates" @default.
- W2093232270 cites W135705743 @default.
- W2093232270 cites W1500615058 @default.
- W2093232270 cites W1608852469 @default.
- W2093232270 cites W1658918516 @default.
- W2093232270 cites W1965775816 @default.
- W2093232270 cites W1965930996 @default.
- W2093232270 cites W1970252081 @default.
- W2093232270 cites W1971711124 @default.
- W2093232270 cites W1975852370 @default.
- W2093232270 cites W1978434981 @default.
- W2093232270 cites W1979352820 @default.
- W2093232270 cites W1979409917 @default.
- W2093232270 cites W1979494733 @default.
- W2093232270 cites W1991348478 @default.
- W2093232270 cites W1993356412 @default.
- W2093232270 cites W1993967654 @default.
- W2093232270 cites W1996787424 @default.
- W2093232270 cites W2002388022 @default.
- W2093232270 cites W2004288558 @default.
- W2093232270 cites W2007886501 @default.
- W2093232270 cites W2008814037 @default.
- W2093232270 cites W2016875024 @default.
- W2093232270 cites W2019603047 @default.
- W2093232270 cites W2019685767 @default.
- W2093232270 cites W2027184893 @default.
- W2093232270 cites W2030056087 @default.
- W2093232270 cites W2030120230 @default.
- W2093232270 cites W2035119178 @default.
- W2093232270 cites W2035319373 @default.
- W2093232270 cites W2043770216 @default.
- W2093232270 cites W2043982952 @default.
- W2093232270 cites W2048665877 @default.
- W2093232270 cites W2062232129 @default.
- W2093232270 cites W2063585355 @default.
- W2093232270 cites W2065362918 @default.
- W2093232270 cites W2068898205 @default.
- W2093232270 cites W2072913347 @default.
- W2093232270 cites W2072991306 @default.
- W2093232270 cites W2083459676 @default.
- W2093232270 cites W2084377677 @default.
- W2093232270 cites W2085427157 @default.
- W2093232270 cites W2085595426 @default.
- W2093232270 cites W2087691402 @default.
- W2093232270 cites W2093412410 @default.
- W2093232270 cites W2093541623 @default.
- W2093232270 cites W2110829590 @default.
- W2093232270 cites W2112364382 @default.
- W2093232270 cites W2121256235 @default.
- W2093232270 cites W2121856052 @default.
- W2093232270 cites W2123458848 @default.
- W2093232270 cites W2133653233 @default.
- W2093232270 cites W2169816250 @default.
- W2093232270 cites W22040801 @default.
- W2093232270 cites W2328930152 @default.
- W2093232270 cites W2522085167 @default.
- W2093232270 cites W286734990 @default.
- W2093232270 cites W375300393 @default.
- W2093232270 cites W99028161 @default.
- W2093232270 doi "https://doi.org/10.1016/j.apcata.2006.09.006" @default.
- W2093232270 hasPublicationYear "2007" @default.
- W2093232270 type Work @default.
- W2093232270 sameAs 2093232270 @default.
- W2093232270 citedByCount "119" @default.
- W2093232270 countsByYear W20932322702012 @default.
- W2093232270 countsByYear W20932322702013 @default.
- W2093232270 countsByYear W20932322702014 @default.
- W2093232270 countsByYear W20932322702015 @default.
- W2093232270 countsByYear W20932322702016 @default.
- W2093232270 countsByYear W20932322702017 @default.
- W2093232270 countsByYear W20932322702018 @default.
- W2093232270 countsByYear W20932322702019 @default.
- W2093232270 countsByYear W20932322702020 @default.
- W2093232270 countsByYear W20932322702021 @default.
- W2093232270 countsByYear W20932322702022 @default.
- W2093232270 countsByYear W20932322702023 @default.
- W2093232270 crossrefType "journal-article" @default.
- W2093232270 hasAuthorship W2093232270A5043956105 @default.
- W2093232270 hasAuthorship W2093232270A5047030779 @default.
- W2093232270 hasAuthorship W2093232270A5071404237 @default.
- W2093232270 hasConcept C161790260 @default.
- W2093232270 hasConcept C178790620 @default.
- W2093232270 hasConcept C185592680 @default.
- W2093232270 hasConcept C21951064 @default.
- W2093232270 hasConcept C2777241282 @default.
- W2093232270 hasConcept C2777628819 @default.
- W2093232270 hasConcept C2777702071 @default.
- W2093232270 hasConcept C2778197717 @default.
- W2093232270 hasConcept C2778704027 @default.
- W2093232270 hasConcept C2780659211 @default.
- W2093232270 hasConcept C505241676 @default.