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• W2093234004 abstract "The role of aqueous phosphate in the selective hydroxylation of cyclohexane to cyclohexanol (60–68% yields) and cyclohexene to 2-cyclohexene-1-ol (98% yield) has been discussed. Fluorinated porphyrins of manganese and iron were used as catalysts in acetonitrile with aqueous-K2HPO4 and t-BuOOH as co-catalyst and oxidant, respectively. The generation of the oxo-manganese reactive intermediate was identified by 1H, 19F NMR, EPR, UV–Vis and mass spectral studies. The formation of phosphate adduct of the oxo-manganese reactive intermediates has been proposed on the basis of high binding constant of dipotassium hydrogen phosphate with the catalyst." @default.
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• W2093234004 date "2010-10-01" @default.
• W2093234004 modified "2023-09-23" @default.
• W2093234004 title "The mechanistic aspects in hydroxylation reactions catalyzed by fluorinated porphyrins of manganese and iron: Role of aqueous phosphate" @default.
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• W2093234004 doi "https://doi.org/10.1016/j.ica.2010.03.071" @default.
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