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- W2093289323 abstract "Im Ames-Test zeigt 9-Hydroxybenzo[a]pyren mutagene Wirkung; man vermutet, daß das labile 4,5-Oxid 1 die reaktive Spezies ist. Es wird aus 9-Benzo[a]pyrenylacetat synthetisiert und mit Ethanthiol abgefangen. Der nucleophile Angriff des Thiolats findet dabei regioselektiv an C-5 von 1 statt. Benzo[a]pyren-4-5-oxid ohne 9-Hydroxygruppe wird dagegen an C-4 und C-5 angegriffen." @default.
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- W2093289323 date "1985-08-01" @default.
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- W2093289323 title "Reaktive Metabolite cancerogener polycyclischer Kohlenwasserstoffe: Synthese und Abfangreaktion von 9-Hydroxybenzo[a]pyren-4,5-oxid" @default.
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- W2093289323 doi "https://doi.org/10.1002/ange.19850970820" @default.
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