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- W2093290471 abstract "We present an integrative laboratory investigation incorporating skills from inorganic chemistry, analytical instrumentation, and physical chemistry applied to a laboratory-scale model of the environmental problem of chlorinated ethylenes in groundwater. Perchloroethylene (C2Cl4, PCE) a common dry cleaning solvent, undergoes sequential replacement of Cl with H to trichloroethylene (C2HCl3) and subsequently cis-dichloroethylene (C2H2Cl2) through catalytic reductive dechlorination with water-soluble cobalt complexes. PCE degradation is monitored by gas chromatography and the first-order rate constants are determined. Experimental conditions may be varied to optimize chlorinated ethylene dechlorination and explore the important parameters governing degradation. Students work with reduction−oxidation active compounds and analyze “real-world” kinetic data sets." @default.
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- W2093290471 date "2010-10-25" @default.
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- W2093290471 title "Degradation of Environmental Contaminants with Water-Soluble Cobalt Catalysts: An Integrative Inorganic Chemistry Investigation" @default.
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- W2093290471 doi "https://doi.org/10.1021/ed1005344" @default.
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