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• W2093298746 endingPage "1557" @default.
• W2093298746 startingPage "1547" @default.
• W2093298746 abstract "Mössbauer spectra of anhydrous ferricyanic acid, H3Fe(CN)6, and alkali metal ferricyanides, M3[Fe(CN)6]. xH2O (where M  Li, Na, Rb, Cs, NH4 and Ag), have been studied at room temperature. These compounds show a two line spectrum indicating definite quadrupole splitting (ΔEQ). The values of ΔEQ range from 0·20 to 0·76 mm/sec. The isomer shifts (δ) vary from 0·08 to 0·26 mm/sec. (relative to sodium nitroprusside dihydrate). The isomer shift shows generally a decreasing trend with the increase in the electronegativity of the substituent cation. It is suggested that the cations influence the π-acceptor property of the cyanide ligands. The s-electron density at the iron nucleus increases as the π-acceptor nature of the ligand increases. The quadrupole splitting data is also consistent with this interpretation. A linear relationship is observed between δ and ΔEQ. The isomer shift for H3Fe(CN)6 is comparatively high presumably due to the presence of intermolecular hydrogen bonding in this compound." @default.
• W2093298746 created "2016-06-24" @default.
• W2093298746 creator A5000905713 @default.
• W2093298746 creator A5046057644 @default.
• W2093298746 date "1970-05-01" @default.
• W2093298746 modified "2023-09-25" @default.
• W2093298746 title "Mössbauer effect studies of alkali metal ferricyanides and hydrogen-bonded ferricyanic acid" @default.
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• W2093298746 doi "https://doi.org/10.1016/0022-1902(70)80642-x" @default.
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