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- W2093346670 abstract "The corrosion behavior of an amorphous Zr40Cu60 alloy in laboratory air (RH = 60 ± 10%) at room temperature was studied by grazing incidence X-ray diffraction (GIXRD) and Auger electron spectroscopy (AES) combined with Ar ion sputter-etching. In general, the corrosion behavior of the roll-side of the specimen which was in contact with the chilling roll during quenching was different from that of the freely solidified surface (top-side). The GIXRD data suggested that monoclinic ZrO2 (m-ZrO2) and tetragonal ZrO2 (t-ZrO2) were formed under a surface layer of metallic copper which was also formed by corrosion of alloy. The t-ZrO2 was distributed more deeply than the m-ZrO2. By AES, it was clarified that a metallic copper layer covered with a very thin ZrO2 was placed in the topmost region, and that, under the copper layer on the roll-side surface, a sandwich structure of ZrO2 and metallic copper was formed, i.e. the corroded region consisted of several layers of ZrO2-rich and copper-rich layers distributed alternatively. On the top side, however, the oxidized layer did not develop significantly and the sandwiched structure of ZrO2 and metallic copper was not observed." @default.
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- W2093346670 date "1997-01-01" @default.
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- W2093346670 title "An auger electron spectroscopic study of the corrosion behavior of an amorphous Zr40Cu60 alloy" @default.
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- W2093346670 doi "https://doi.org/10.1016/s0010-938x(96)00108-4" @default.
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