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- W2093348291 abstract "Alkylation and aldol reactions carried out on axially chiral, diastereoenriched oxazolidinedione derivatives were found to be highly stereoselective with respect to substitution at the 5-position of the oxazolidindione ring. Thus, diastereoenriched 5-methyl-3-( o -iodophenyl)-2-thioxo-4-oxazolidinone and 5-methyl-3-( o -aryl)-2,4-oxazolidinediones were prepared and lithiated at C-5 of the oxazolidine ring and the subsequent electrophilic quench with alkyl halides or benzaldehyde yielded products with the same diastereomer ratios as the starting materials." @default.
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- W2093348291 date "2010-10-01" @default.
- W2093348291 modified "2023-09-26" @default.
- W2093348291 title "Stereoselective lithiation and alkylation and aldol reactions of chiral 5-methyl-3-(o-aryl)-oxazolidinones" @default.
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- W2093348291 doi "https://doi.org/10.1016/j.tetasy.2010.10.008" @default.
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