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- W2093350991 abstract "Fluorotrifluoromethylsulphine (CF3.CFSO, 1), the first stable perfluoroalkylsulphine has been synthesised recently in our laboratories. An alternative route to (1) and a route to other perfluoroalkylsulphines RFCFSO arise via the dechlorofluorination of perfluoroalkylsulphinyl chlorides (RFCF2.SOCl, 2), readily available from the corresponding sulphonyl halides. Thermal dechlorofluorination of the sulphinyl chlorides (2) over copper at approximately 250° gives the corresponding sulphines. In contrast, at temperatures around 200°, the reaction of the sulphinyl chlorides (2) with copper gives the perfluoroalkylthiosulphonates (RFS.SO2RF), which are also prepared from the sulphinyl chlorides (2) and mercury at room temperature." @default.
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- W2093350991 date "1982-09-01" @default.
- W2093350991 modified "2023-09-25" @default.
- W2093350991 title "Preparation of some perfluoroalkylsulphines" @default.
- W2093350991 doi "https://doi.org/10.1016/s0022-1139(00)85433-0" @default.
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