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- W2093387172 abstract "The widely employed approach to self-assembly of fullerene derivatives on gold can be complicated due to multilayer formations and head-to-tail assemblies resulting from the strong fullerene−fullerene and fullerene−gold interactions. These anomalies were not examined in detail in previous studies on fullerene self-assembled monolayers (SAMs) but were clearly detected in the present work using surface characterization techniques including ellipsometry, cyclic voltammetry (CV), and X-ray photoelectron spectroscopy (XPS). This is the first time that SAMs prepared from fullerene derivatives of thiols/thiol esters/disulfides have been analyzed in detail, and the complications due to multilayer formations and head-to-tail assemblies were revealed. Specifically, we designed and synthesized several fullerene derivatives based on thiols, thiol acetates, and disulfides to address the characterization requirements, and these are described and delineated. These studies specifically address the need to properly characterize and control fullerene−thiol assemblies on gold before evaluating subsequent device performances." @default.
- W2093387172 created "2016-06-24" @default.
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- W2093387172 date "2006-09-23" @default.
- W2093387172 modified "2023-10-17" @default.
- W2093387172 title "Characterization of Self-Assembled Monolayers of Fullerene Derivatives on Gold Surfaces: Implications for Device Evaluations" @default.
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- W2093387172 doi "https://doi.org/10.1021/ja063451d" @default.
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