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- W2093387795 abstract "Lewis acid-promoted reactions of peracetylated sugars (glucose, galactose, maltose, lactose) with omega-bromo-1-alkanols (C(8), C(12)) were investigated. ZnCl(2) was found to promote the 1,2-trans-glycosylation of the alcohols in toluene at about 60 degrees C in a stereocontrolled manner with better yields than commonly employed promoters such as SnCl(4). The omega-bromoalkyl acetylated glycosides were readily converted to omega-mercaptoalkyl glycosides, which are useful for the preparation of glycoclusters." @default.
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- W2093387795 date "2007-06-01" @default.
- W2093387795 modified "2023-09-24" @default.
- W2093387795 title "Efficient synthesis of ω-mercaptoalkyl 1,2-trans-glycosides from sugar peracetates" @default.
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- W2093387795 doi "https://doi.org/10.1016/j.carres.2007.02.024" @default.
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