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- W2093440894 abstract "Abstract Molar excess enthalpies HE were measured in a McGlashan-type calorimeter over the whole range of mole fraction x at 298.15 K and for x ≈ 0.5 at 288.15 K. One component was invariably dichloromethane, the other component being 1-n-, cis-2-, trans-2-, cis-3-, or trans-3-hexene, or 1-n-heptene, 1-n-octene, 1-n-nonene, 1-n-decene, or 1,3-hexadiene, 1,5-hexadiene, or cyclohexene, or 1,3-cyclohexadiene and 1,4-cyclohexadiene. Analysis of the results suggests the occurrence of specific interactions in these mixtures and indicates the considerable role of inductive action of the polar molecule of dichloromethane on the π bond in the unsaturated compound. The effect is presented of the molecular size of the chloro-derivatives of methane on the difference in HE between their mixtures with the cis- and the trans-alkenes. The results of the investigations performed so far on mixtures of unsaturated hydrocarbons with chloroderivatives of methane are summarized." @default.
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- W2093440894 date "1980-08-01" @default.
- W2093440894 modified "2023-09-27" @default.
- W2093440894 title "Excess enthalpies of binary mixtures containing unsaturated hydrocarbons 8. Dichloromethane + n-alkene and + n-diene" @default.
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- W2093440894 doi "https://doi.org/10.1016/0021-9614(80)90174-3" @default.
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