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• W2093441110 endingPage "597" @default.
• W2093441110 startingPage "591" @default.
• W2093441110 abstract "Electrospray ionization mass spectrometry was used to study the photodegradation of an oil sands naphthenic acid (NA) mixture, a commercial Fluka NA mixture and a candidate NA, 4-Methyl-cyclohexaneaceticic acid (4-MCHAA) irradiated with TiO(2) (P25) suspension under both fluorescent and natural sunlight. Under natural sunlight irradiation over the TiO(2) suspension, approximately 75% of compounds in the NA mixtures and 100% of 4-MCHAA were degraded in 8 h. No degradation was observed under dark conditions, regardless of the presence or absence of TiO(2). The structural formula of the NAs is given by C(n)H(2n + z)O(2), where n represents the carbon number and z specifies a homologous family with 0-6 rings (z = 0 to -12). The degree of degradation was noted to vary among the NA mixtures and the candidate NA compound with more efficient degradation achieved for molecules with -z values from 0 to 6. The difference in the efficacy of the photocatalysis was likely due to the structure and size of the compounds. In the case of -z = 6 to 12, steric constraints are a key factor what hinders photocatalysis." @default.
• W2093441110 created "2016-06-24" @default.
• W2093441110 creator A5057988839 @default.
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• W2093441110 date "2009-04-10" @default.
• W2093441110 modified "2023-10-01" @default.
• W2093441110 title "Electrospray ionization mass spectrometry of the photodegradation of naphthenic acids mixtures irradiated with titanium dioxide" @default.
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• W2093441110 doi "https://doi.org/10.1080/10934520902784625" @default.
• W2093441110 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19337922" @default.
• W2093441110 hasPublicationYear "2009" @default.
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