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- W2093441569 abstract "In work directed towards the synthesis of functionalized diaryl ethers such as SK + F L-94901 the benzylic carbanion derived from 3-ethoxy-6-methylpyridazine-1-oxide was added ortho to an electron-withdrawing chlorine group in (η5 -cyclopentadienyl)(η6-1,4-dichlorobenzene)iron(1 +) hexafluorophosphate(1 − ) and other η6-chloroarene cationic complexes to form neutral η5-cyclohexadienyl ligands. Oxidative aromatization of the adduct occurred with concomitant demetallation. In contrast to the Yanovsky-type reactions of the carbanion, chloride was displaced from (η6-1,4-dichlorobenzene)CpFe+ by phenoxide anions under mild conditions to give η6-diphenyl ether cationic complexes." @default.
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- W2093441569 date "1992-08-01" @default.
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- W2093441569 title "Functionalization of chlorobenzenes via their CpFe+ salts: A synthesis of substituted diphenyl ethers" @default.
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- W2093441569 doi "https://doi.org/10.1016/0022-328x(92)83357-n" @default.
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