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- W2093450966 abstract "Chlorobis(2,2,2-trichloroethoxy)- and dichloro(2,2,2-trichloroethoxy)iron(III) have been synthesized. They react with various oxygen and nitrogen donor ligands to yield adducts formulated as FeCl(OCH2CCl3)2 · 2 L or FeCl2(OCH2CCl3) · 2 L (L = ligand). The depressed magnetic moments of these compounds show the presence of strong antiferromagnetic interactions between iron atoms. The infrared and 1H nmr spectra establish the presence of bridging and terminal alkoxy groups and ligands (L) are cis to each other. The electronic spectra of these complexes indicate that each iron atom is approximately octahedrally coordinated. Mass spectral data are in favour of dimeric structure for the title compounds. Chlorobis(2, 2, 2-trichlorethoxid)- und Dichloro(2, 2, 2,-trichlorethoxid)eisen(III) Die Titelverbindungen wurden dargestellt. Sie reagieren mit verschiedenen Sauerstoff- und Stickstoff-Donorliganden unter Bildung von Addukten wie FeCl(OCH2CCl3)2 · 2 L bzw. FeCl2(OCH2CCl3) · 2 L. Die erniedrigten magnetischen Momente dieser Verbindungen deuten auf starke antiferromagnetische Wechselwirkung zwischen den Eisenatomen. Die IR- und 1H-NMR-Spektren zeigen das Vorliegen von verbrückten und endständigen Alkoxidgruppen und von Liganden in cis-Stellung. Die Elektronenspektren zeigen, daß die Eisenatome annähernd oktaedrisch koordiniert sind. Die Massenspektren deuten auf eine dimere Struktur der Titelverbindungen." @default.
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- W2093450966 date "1987-02-01" @default.
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- W2093450966 title "Chlorobis(2,2,2-trichloroethoxy)-and dichloro(2,2,2-trichloroethoxy)-iron(III): Synthesis, characterization, and coordination chemistry" @default.
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- W2093450966 doi "https://doi.org/10.1002/zaac.19875450228" @default.
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