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• W2093485993 abstract "The benzylic carbonates, which connect with an active methine through an o-phenylene tether at their meta-position, are cyclized by Pd(η3-C3H5)Cp–S-Phos catalyst, yielding 3-methyl-9,10-dihydrophenanthrenes. In the catalytic cyclization, the internal nucleophile attacks not the ortho-carbon but the para-carbon of the benzylic ester. The [3 + 2] cycloaddition of m-(silylmethyl)benzyl carbonates with alkylidene malonates was developed from the palladium-catalyzed intramolecular SN′-type aromatic substitution." @default.
• W2093485993 created "2016-06-24" @default.
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• W2093485993 date "2011-12-02" @default.
• W2093485993 modified "2023-10-17" @default.
• W2093485993 title "Intramolecular S_N′-Type Aromatic Substitution of Benzylic Carbonates at their Para-Position" @default.
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• W2093485993 doi "https://doi.org/10.1021/ol203089k" @default.
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