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- W2093496757 abstract "1,3-Dipolar cycloaddition of azomethine ylides to C60 leads to fulleroproline derivatives, in which a proline ring is fused on a 6,6-ring junction of the fullerene spheroid. This unnatural amino acid can be manipulated under standard coupling conditions to afford fulleroproline-containing peptides. All optically active fulleroproline derivatives and peptides display a characteristic maximum at 428 nm in CD spectra, which is diagnostic for the assignment of the absolute configuration of the Cα atom of the proline ring. Calculation of the CD spectra confirm the configurational assignment." @default.
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- W2093496757 date "1996-01-01" @default.
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- W2093496757 title "Synthesis, Chiroptical Properties, and Configurational Assignment of Fulleroproline Derivatives and Peptides" @default.
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- W2093496757 doi "https://doi.org/10.1021/ja9539249" @default.
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