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• W2093526147 endingPage "4462" @default.
• W2093526147 startingPage "4457" @default.
• W2093526147 abstract "Diorganohydrazido(2–) complexes of tungsten (L)Cl4W(NNR2) [R2 = Me2, Ph2, –(CH2)5–; L = CH3CN, pyridine] were synthesized by reacting the corresponding 1,1-diorganohydrazine with WCl6, followed by reaction with acetonitrile or pyridine. Crystallographic structure determination of (CH3CN)Cl4W(NNMe2) and (CH3CN)Cl4W(NNPh2) allows a comparison of the structural features of the diorganohydrazido(2–) functionality with varying substituents. Mass spectrometry, thermogravimetric analysis, and preliminary chemical vapor deposition experiments were performed to determine the viability of these complexes as single-source precursors for deposition of WNx and WNxCy films." @default.
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• W2093526147 date "2007-09-15" @default.
• W2093526147 modified "2023-09-24" @default.
• W2093526147 title "Synthesis and Characterization of Diorganohydrazido(2–) Tungsten Complexes" @default.
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• W2093526147 doi "https://doi.org/10.1021/ic701151m" @default.
• W2093526147 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17867680" @default.
• W2093526147 hasPublicationYear "2007" @default.
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