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- W2093540116 abstract "NQR signals from 209Bi have been observed for the axially symmetric Bi3+ site in the isostructural series BiOF, BiOCI, BiOBr, BiOI. The quadrupole coupling constants at 295 K were 272.94, 152.46, 119.58, and 91.26 MHz; respectively. A lattice-sum calculation of the electric field gradient at the Bi3+ site, based on the self-consistent monopole charge-point dipole model, underestimates the magnitude of the quadrupole coupling constants but suggests that the dipole moment induced on the bismuth ion determines the trend in the coupling constants. An alternative explanation of the trend of coupling constants for the bismuth oxyhalides is given, based on a Townes-Dailey analysis of dsp3 or d2p3 hybrid molecular orbitals on the Bi3+ ion." @default.
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- W2093540116 date "1977-06-01" @default.
- W2093540116 modified "2023-10-16" @default.
- W2093540116 title "Nuclear quadrupole resonance of 209Bi in bismuth oxylhalides" @default.
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- W2093540116 doi "https://doi.org/10.1016/0022-2364(77)90097-x" @default.
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