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- W2093544872 abstract "The ligand exchange reactions between cyclopalladated complexes and free N-donor ligands have been studied, and the sequence of the stabilities of such complexes established. The five-membered complexes derived from 2-phenylpyridine, and the six-membered complexes derived from mesitylenamines with PdC aliphatic bonds are the most stable, and the complexes derived from amines are less stable. The results suggest that the relative stabilities of these cyclometallated compounds cannot be related solely to one of the factors considered, viz. the size of the metallocycle and the nature of the carbon or nitrogen atoms bonded to the metal." @default.
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- W2093544872 date "1989-02-01" @default.
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- W2093544872 title "Ligand exchange reactions of N-donor ligands in cyclopalladated complexes" @default.
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- W2093544872 doi "https://doi.org/10.1016/0022-328x(89)87009-3" @default.
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