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- W2093552844 abstract "NMR lineshapes obtained by Fourier transform of the solid-echo decay are compared with those from the free-induction decay in the slow-motion region where the motional correlation times are of the same order as the reciprocal anisotropic spin interactions. The theory has been worked out explicitly for the example of two-site exchange in an I = 1 spin system that applies, e.g., to 1H or 2D NMR of water molecules flipping by 180° about the twofold axis. Large differences are found in the region where the time between the two 90° pulses of the solid-echo sequence is comparable with the motional correlation time. The intensity of the solid echo is reduced by a factor R > 0.5 relative to the free-induction decay for the example of anisotropic motion considered. Much smaller reduction factors are obtained for isotropic reorientation by small- or large-angle rotational jumps." @default.
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- W2093552844 date "1981-03-01" @default.
- W2093552844 modified "2023-10-17" @default.
- W2093552844 title "Solid echoes in the slow-motion region" @default.
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- W2093552844 doi "https://doi.org/10.1016/0022-2364(81)90256-0" @default.
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