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- W2093552924 abstract "The guanidinium protonation constant pKa2 of l-canavanine has been determined in aqueous solution at different temperatures and different ionic strengths, using a potentiometry technique. The effect of an organic solvent added to the aqueous solution on the protonation processes is also reported and explained. The organic solvents used were methanol, dimethylformamide (DMF), dimethylsulfoxide (DMSO), acetone, and dioxane. The pKa2 values for the ionization in a water (1) + dioxane (2) mixture have been determined at four different temperatures from T = (298.15 to 328.15) K. Finally, the thermodynamic quantities (ΔH° and ΔS°) associated with this protonation process were calculated and discussed." @default.
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- W2093552924 date "2010-07-27" @default.
- W2093552924 modified "2023-10-17" @default.
- W2093552924 title "Guanidinium Protonation Equilibria of <scp>l</scp>-Canavanine in Different Ionic Media" @default.
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- W2093552924 doi "https://doi.org/10.1021/je100292g" @default.
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