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- W2093574967 abstract "X-ray absorption near edge structure (XANES) of halogen-bridged mixed-valence Pt complexes and halogen-bridged Pd-Pt mixed-metal complexes have been measured using synchrotron radiation with a high energy resolution. In Pd-Pt mixed metal complexes, we demonstrate that the degree of the valence is estimated from the intensity of the white line at the Pt L3 edge. In the mixed-valence complexes, the electron system is proved to be the Peierls insulator with a charge density wave of renormalized d electrons of Pt, where the total valence of PtIV- and Pt11 is conserved without excess electrons from ligands or anions." @default.
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- W2093574967 date "1985-03-01" @default.
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- W2093574967 title "PT L3 near edge structure of halogen-bridged mixed-valence pt complexes and pd-pt mixed-metal complexes" @default.
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- W2093574967 doi "https://doi.org/10.1016/0038-1098(85)90467-3" @default.
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