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- W2093575210 abstract "Reaction of the new biguanidine (iPr)HN{NH(iPr)}CN(CH2)2NC{NH(iPr)}N(iPr)H (1) with M(CH2Ph)4 affords the hydrocarbyl complexes [iPrN{NH(iPr)}CN(CH2)2NC{NH(iPr)}NiPr]M(CH2Ph)2 ([L4Pr]M(CH2Ph)4; M = Ti (2), Zr (3)). Structure determinations of 2 and 3 and the reactivity of 3 with 2,6-dimethylphenyl isocyanide indicate that the linked guanidinate ligand system provides a more open metal coordination sphere than do the unlinked analogues." @default.
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- W2093575210 date "2003-01-01" @default.
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- W2093575210 title "Redefining the Coordination Geometry and Reactivity of Guanidinate Complexes by Covalently Linking the Guanidinate Ligands. Synthesis and Reactivity of [RN{NH(R)}CN(CH<sub>2</sub>)<sub>2</sub>NC{NH(R)}NR]M(CH<sub>2</sub>Ph)<sub>2</sub> (R = <sup>i</sup>Pr; M = Ti, Zr)" @default.
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- W2093575210 doi "https://doi.org/10.1021/om020830g" @default.
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