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- W2093583350 abstract "Diastereomeric pipecolates 3 and 7 can be obtained from either syn-1 or anti-1. The stereochemical complexity was increased further by subjecting 3 and 7 to the reaction with chiral epoxides (R)-4 or (S)-4 bearing various substituents. Thus, a number of diastereomeric pyridooxazidinones 5, 6, 8 or 9 can be synthesized in six or seven steps, with all stereocenters well defined. The azido analogs of 5, 6, 8 and 9 were shown to undergo a Staudinger-reductive amination-transesterification sequence to yield the pyridodiazepinones 10 ." @default.
- W2093583350 created "2016-06-24" @default.
- W2093583350 date "2007-05-22" @default.
- W2093583350 modified "2023-09-25" @default.
- W2093583350 title "Stereocontrolled Synthesis of Pyridooxazinones and Pyridodiazepinones" @default.
- W2093583350 doi "https://doi.org/10.1055/s-2007-968559" @default.
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