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• W2093583387 abstract "The kinetics of one-dimensional gel swelling and collapse for large volume changes were described by a Fickian model which accounts for the movement of the gel surface. For a constant mutual diffusion coefficient, Dm, the fractional approach to equilibrium, F, is a function only of dimensionless time, τ0, and the equilibrium volume ratio, Φ. Gel collapse is faster than swelling when Dm is the same for both. Swelling curves, the variation of F with ✓τ0, were computed for planar, cylindrical and spherical geometries with constant Dm. For slabs the swelling curves are initially linear for all Φ values, while for cylinders and spheres the swelling curves are linear for small Φ values, but sigmoidal for Φ ≥ 2.5. For 0.5 ≤ Φ ≤ 2, a simple method gives experimental values of Dm which account for the movement of the gel boundary. Experimental data for weakly ionic poly(N-isopropylacrylamide) gel spheres in water (Φ = 55) and for non-ionic poly(N-isopropylacrylamide) gel disks in water (Φ = 7.7) were well fitted by the model." @default.
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• W2093583387 date "1996-10-01" @default.
• W2093583387 modified "2023-09-23" @default.
• W2093583387 title "Kinetics of one-dimensional gel swelling and collapse for large volume change" @default.
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• W2093583387 doi "https://doi.org/10.1016/0009-2509(96)00254-0" @default.
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