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- W2093583609 abstract "1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) catalyzed esterification with 1-bromooctane over tetrakis/octakis(carboxy)phthalocyanines originated from trimellitic anhydride and pyromellitic dianhydride led to the isolation of a series of 2(3),9(10),16(17),24(25)-tetrakis(octyloxycarbonyl)phthalocyaninato metal complexes M[Pc(COOC8H17)4] (MCo, Ni, Cu, Zn) (1a–1d) and 2,3,9,10,16,17,24,25-octakis(octyloxycarbonyl)phthalocyaninato metal complexes M[Pc(COOC8H17)8] (MCo, Cu) (2a, 2c). In addition to elemental analysis, these tetrakis/octakis(octyloxycarbonyl)-substituted phthalocyanines were characterized by a series of spectroscopic methods including MALDI-TOF mass, 1H NMR and 2D COSY, UV–vis, and IR spectroscopy. The tetrakis(octyloxycarbonyl)-substituted phthalocyanines represent the first example of 2(3),9(10),16(17),24(25)-tetrakis(octyloxycarbonyl)phthalocyaninato metal complexes that have ever been unambiguously characterized by mass and NMR spectroscopy." @default.
- W2093583609 created "2016-06-24" @default.
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- W2093583609 date "2013-02-01" @default.
- W2093583609 modified "2023-09-27" @default.
- W2093583609 title "Trimellitic anhydride- and pyromellitic dianhydride-originated tetrakis/octakis(octyloxycarbonyl)phthalocyaninato metal complexes" @default.
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- W2093583609 doi "https://doi.org/10.1016/j.inoche.2012.11.021" @default.
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