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- W2093584518 abstract "The Hosomi-Sakurai reactions of E- and Z-crotylsilanes with cyclohexenone at −78 °C showed respectively high erythro and relatively low threo selectivities, modification of the silyl substituents giving a variable effect. In the reaction with Z-alkoxycrotylsilanes, the threo selectivity could be improved by the utilization of the kinetic difference between the diastereomeric products 4 and 5 to the secondary cyclization. Starting from 4 and 4 thus obtained, the syntheses of both (±)-juvabione and (±)-epi-juvabione have been respectively achieved in a concise way." @default.
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- W2093584518 date "1989-01-01" @default.
- W2093584518 modified "2023-10-08" @default.
- W2093584518 title "Efficient stereoselective syntheses of both (±)-juvabione and (±)-epi-juvabione by new extracyclic stereocontrol methodology" @default.
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- W2093584518 doi "https://doi.org/10.1016/s0040-4039(00)95158-x" @default.
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