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• W2093585613 abstract "A variety of reactions occur between trans-[OsVI(tpy)(Cl)2(N)]+ (1) (tpy = 2,2‘:6‘,2‘‘-terpyridine) or [OsVI(tpm)(Cl)2(N)]+ (2) (tpm = tris(1-pyrazolyl)methane) and N3-. The reaction between 2 and N3- gives the stable dinitrogen complex OsII(tpm)(Cl)2(N2), but with 1 the chemistry is solvent dependent. One-electron reduction to give trans,trans-(tpy)(Cl)2OsII(N2)OsII(Cl)2(tpy) occurs in nonpolar solvents. 1 and 2 react with N3- in the presence of CS2 to give the thionitrosyls [OsII(L3)(Cl)2(NS)]+ (L3 = tpy, tpm), -SCN, and N2. A reaction between 1 and excess N3- in CH3CN occurs to give the first OsIII-5-CH3-tetrazolate complex, and it has been characterized by X-ray crystallography (structure shown)." @default.
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• W2093585613 date "1998-02-10" @default.
• W2093585613 modified "2023-10-16" @default.
• W2093585613 title "Reactivity of Osmium(VI) Nitrides with the Azide Ion" @default.
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• W2093585613 doi "https://doi.org/10.1021/ic971336l" @default.
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