Matches in SemOpenAlex for { <https://semopenalex.org/work/W2093586687> ?p ?o ?g. }
Showing items 1 to 89 of
89
with 100 items per page.
- W2093586687 abstract "Abstract A kinetic study of the reaction between [Pt(Bipy)(Am)Cl]+ complexes (Am = ethanolamine or propanolamine) and CH3O− in methanol is reported. The kinetic rate law of the process is: k obs = k 1 + k 2 [ CH 3 O − ] The k1 term is interpreted assuming an attack of the alcoholic group on Am on the PtII. The k2 term is interpreted considering a rapid acid-base pre-equilibrium leading to an alkoxy intermediate complex followed by the rate determining displacement of the halide ion by the alkoxide group. The effect of the length of the chain (Am) on the rate is also discussed." @default.
- W2093586687 created "2016-06-24" @default.
- W2093586687 creator A5027358166 @default.
- W2093586687 creator A5047291400 @default.
- W2093586687 creator A5056932242 @default.
- W2093586687 creator A5077899434 @default.
- W2093586687 date "1975-06-01" @default.
- W2093586687 modified "2023-09-26" @default.
- W2093586687 title "Anchimeric assistence in the reaction of [Pt(Bipy)(NH2(CH2)nOH)Cl]+ complexes" @default.
- W2093586687 cites W2000961154 @default.
- W2093586687 cites W2004284860 @default.
- W2093586687 cites W2017513896 @default.
- W2093586687 cites W2045985082 @default.
- W2093586687 cites W2079833281 @default.
- W2093586687 cites W2149479160 @default.
- W2093586687 cites W2314720395 @default.
- W2093586687 cites W2320553523 @default.
- W2093586687 cites W2921061219 @default.
- W2093586687 doi "https://doi.org/10.1016/0022-1902(75)80791-3" @default.
- W2093586687 hasPublicationYear "1975" @default.
- W2093586687 type Work @default.
- W2093586687 sameAs 2093586687 @default.
- W2093586687 citedByCount "4" @default.
- W2093586687 crossrefType "journal-article" @default.
- W2093586687 hasAuthorship W2093586687A5027358166 @default.
- W2093586687 hasAuthorship W2093586687A5047291400 @default.
- W2093586687 hasAuthorship W2093586687A5056932242 @default.
- W2093586687 hasAuthorship W2093586687A5077899434 @default.
- W2093586687 hasConcept C121332964 @default.
- W2093586687 hasConcept C135889238 @default.
- W2093586687 hasConcept C145148216 @default.
- W2093586687 hasConcept C155647269 @default.
- W2093586687 hasConcept C161790260 @default.
- W2093586687 hasConcept C171560689 @default.
- W2093586687 hasConcept C175113610 @default.
- W2093586687 hasConcept C178790620 @default.
- W2093586687 hasConcept C179104552 @default.
- W2093586687 hasConcept C185592680 @default.
- W2093586687 hasConcept C2778839380 @default.
- W2093586687 hasConcept C2779216040 @default.
- W2093586687 hasConcept C2779607525 @default.
- W2093586687 hasConcept C2780263894 @default.
- W2093586687 hasConcept C62520636 @default.
- W2093586687 hasConcept C71240020 @default.
- W2093586687 hasConcept C90150868 @default.
- W2093586687 hasConceptScore W2093586687C121332964 @default.
- W2093586687 hasConceptScore W2093586687C135889238 @default.
- W2093586687 hasConceptScore W2093586687C145148216 @default.
- W2093586687 hasConceptScore W2093586687C155647269 @default.
- W2093586687 hasConceptScore W2093586687C161790260 @default.
- W2093586687 hasConceptScore W2093586687C171560689 @default.
- W2093586687 hasConceptScore W2093586687C175113610 @default.
- W2093586687 hasConceptScore W2093586687C178790620 @default.
- W2093586687 hasConceptScore W2093586687C179104552 @default.
- W2093586687 hasConceptScore W2093586687C185592680 @default.
- W2093586687 hasConceptScore W2093586687C2778839380 @default.
- W2093586687 hasConceptScore W2093586687C2779216040 @default.
- W2093586687 hasConceptScore W2093586687C2779607525 @default.
- W2093586687 hasConceptScore W2093586687C2780263894 @default.
- W2093586687 hasConceptScore W2093586687C62520636 @default.
- W2093586687 hasConceptScore W2093586687C71240020 @default.
- W2093586687 hasConceptScore W2093586687C90150868 @default.
- W2093586687 hasLocation W20935866871 @default.
- W2093586687 hasOpenAccess W2093586687 @default.
- W2093586687 hasPrimaryLocation W20935866871 @default.
- W2093586687 hasRelatedWork W1599375777 @default.
- W2093586687 hasRelatedWork W1808803502 @default.
- W2093586687 hasRelatedWork W1965147029 @default.
- W2093586687 hasRelatedWork W1973493883 @default.
- W2093586687 hasRelatedWork W1977044141 @default.
- W2093586687 hasRelatedWork W1988438541 @default.
- W2093586687 hasRelatedWork W2015037943 @default.
- W2093586687 hasRelatedWork W2038978029 @default.
- W2093586687 hasRelatedWork W2049587794 @default.
- W2093586687 hasRelatedWork W2050239494 @default.
- W2093586687 hasRelatedWork W2056936829 @default.
- W2093586687 hasRelatedWork W2098570143 @default.
- W2093586687 hasRelatedWork W2145376023 @default.
- W2093586687 hasRelatedWork W2314334386 @default.
- W2093586687 hasRelatedWork W2333100149 @default.
- W2093586687 hasRelatedWork W2901691940 @default.
- W2093586687 hasRelatedWork W2925505030 @default.
- W2093586687 hasRelatedWork W2951769851 @default.
- W2093586687 hasRelatedWork W2953058542 @default.
- W2093586687 hasRelatedWork W3159621051 @default.
- W2093586687 isParatext "false" @default.
- W2093586687 isRetracted "false" @default.
- W2093586687 magId "2093586687" @default.
- W2093586687 workType "article" @default.