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- W2093586885 abstract "Abstract The complex [M(CO) 3 {S 2 P(OEt) 2 } 2 ] (M=Mo, W) can be obtained in situ from the reaction of [MI 2 (CO) 3 (NCMe) 2 ] with ammoniumdiethyldithiophosphate, in dichloromethane. One or two carbonyl groups can be replaced by mono and bidentate phosphines, such as Ph 2 PCH 2 PPh 2 (dppm), Ph 2 P(CH 2 ) 2 PPh 2 (dppe), or PPh 3 , to afford heptacoordinate complexes [M(CO) 2 (PPh 3 ){S 2 P(OEt) 2 } 2 ] (M=Mo, 2a ; W, 2b ), [M(CO) 2 {S 2 P(OEt) 2 } 2 ] 2 (μ-dppe) (M=Mo, 3a ; W, 3b ), [M(CO)(dppm){S 2 P(OEt) 2 } 2 ] (M=Mo, 4a ; W, 4b ), [Mo(CO)(dppe){S 2 P(OEt) 2 } 2 ] ( 5a ), [W(CO) 2 (dppe){S 2 P(OEt) 2 } 2 ] ( 6b ), and [Mo(O)(I)(dppe){S 2 P(OEt) 2 }] ( 7a ). All these complexes, with the exception of 4b , were structurally characterized by single crystal X-ray diffraction. The capped octahedral geometry was observed in all biscarbonyl species, the CO being the capping ligand. Complex 4a exhibits a pentagonal bipyramidal arrangement, with the carbonyl occupying one axial position, while 7a is an octahedral complex. These complexes were studied by cyclic voltammetry, showing essentially irreversible processes, involving orbitals with a strong d character." @default.
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- W2093586885 date "2001-08-01" @default.
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- W2093586885 title "Heptacoordinate dithiophosphate Mo(II) and W(II) complexes: molecular structures of mono and binuclear phosphine complexes" @default.
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- W2093586885 doi "https://doi.org/10.1016/s0022-328x(01)00989-5" @default.
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