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- W2093597617 abstract "Abstract A series of arguments, based on experimental results concerning mainly methane and ethane, in favour of an associative mechanism of the hydrocarbon with an adsorbed H atom for the adsorption step of alkanes on metal surfaces are reviewed. The reaction scheme for the adsorption step is written: As w has a smaller value than z, a coverage function in hydrogen, of the type (1-θH)Z if the adsorption step is rate determining, or (1-θH)Z-W if the adsorption step is near to equilibrium, contributes to the kinetic equation of the catalytic reaction. Due to the large value of z (8 or more), this function contains a hydrogen pressure and a temperature dependence of the same type as measured on the rate of the catalytic reaction. It also contains a demanding character." @default.
- W2093597617 created "2016-06-24" @default.
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- W2093597617 date "1992-02-01" @default.
- W2093597617 modified "2023-09-26" @default.
- W2093597617 title "Adsorption site of alkanes on metals and associated hydrogen pressure effects" @default.
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- W2093597617 doi "https://doi.org/10.1016/0920-5861(92)85035-k" @default.
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