Matches in SemOpenAlex for { <https://semopenalex.org/work/W2093626532> ?p ?o ?g. }
- W2093626532 endingPage "101" @default.
- W2093626532 startingPage "79" @default.
- W2093626532 abstract "A detailed sequential extraction scheme (MESEX) was developed to distinguish Fe and Mn phases in eastern Mediterranean sediments. After calibration and validation using single natural minerals and a mixed mineral standard, MESEX was applied to Holocene eastern Mediterranean sediments from (1) a former brine basin, and (2) a normal setting, including the organic-rich sapropel S1. In both sediments the Mn(II)/Mn(III,IV) redox boundary is clearly distinguished with carbonate-related Mn being enriched below, and Mn oxides occurring only above it. A clear Fe(II)/Fe(III) redox boundary is present in the normal eastern Mediterranean sediments and is located just below the Mn(II)/Mn(III,IV) redox boundary. The Fe(II)/Fe(III) boundary closely coincides with the visible boundary between the lower unoxidised and the upper oxidised (burned-down) part of the original sapropel S1 interval. Pyrite is only present within the unoxidised interval, whereas Fe oxides are abundant above it. The Fe(II)/Fe(III) redox boundary in the former brine sediments resides on top of the organic-enriched sediments, as deduced from the distribution of Fe oxides and pyrite. As a result of burn-down of the sapropel S1 unit in the normal sediments, a vanadium peak has been formed below the oxidation front, whereas no such V peak was observed in the former brine sediments. This, together with the location of the Mn(II)/Mn(III,IV) redox boundary well above the organic-enriched sediments, suggests that no burn-down has taken place into the sapropelic sediments of the former brine basin, resulting in the preservation of the relationships of trace metal to organic carbon or pyrite. In these latter sediments, Mn and Co appear to be associated with pyrite, whereas Ni, Cu and Zn, as well as V, are more related to organic matter. On the basis of MESEX, variations have also been detected in the terrigenous component, i.e. aluminosilicates. (Fe/Al)clay, (Mg/Al)clay, and several trace metal to Al ratios are higher in sapropelic than in non-sapropelic sediments. These results indicate that sources of terrestrial material have been different during sapropel times compared to the period immediately after it. On the other hand, the fairly constant K/Alclay ratio suggests that no major changes may have occurred in the relative illite contribution." @default.
- W2093626532 created "2016-06-24" @default.
- W2093626532 creator A5004212104 @default.
- W2093626532 creator A5007139291 @default.
- W2093626532 date "2003-01-01" @default.
- W2093626532 modified "2023-09-26" @default.
- W2093626532 title "Sequential extraction of iron, manganese and related elements in S1 sapropel sediments, eastern Mediterranean" @default.
- W2093626532 cites W1006909939 @default.
- W2093626532 cites W1965430736 @default.
- W2093626532 cites W1971369540 @default.
- W2093626532 cites W1975061192 @default.
- W2093626532 cites W1977457680 @default.
- W2093626532 cites W1978096124 @default.
- W2093626532 cites W1979945780 @default.
- W2093626532 cites W1982691560 @default.
- W2093626532 cites W1988218245 @default.
- W2093626532 cites W1991068870 @default.
- W2093626532 cites W2003544527 @default.
- W2093626532 cites W2005021733 @default.
- W2093626532 cites W2008450675 @default.
- W2093626532 cites W2011948678 @default.
- W2093626532 cites W2017079901 @default.
- W2093626532 cites W2021301016 @default.
- W2093626532 cites W2024645652 @default.
- W2093626532 cites W2026662825 @default.
- W2093626532 cites W2031304694 @default.
- W2093626532 cites W2035398133 @default.
- W2093626532 cites W2040701129 @default.
- W2093626532 cites W2043668123 @default.
- W2093626532 cites W2046957942 @default.
- W2093626532 cites W2051947331 @default.
- W2093626532 cites W2057798545 @default.
- W2093626532 cites W2059245554 @default.
- W2093626532 cites W2061785747 @default.
- W2093626532 cites W2075944686 @default.
- W2093626532 cites W2081893898 @default.
- W2093626532 cites W2082225456 @default.
- W2093626532 cites W2082657419 @default.
- W2093626532 cites W2086474520 @default.
- W2093626532 cites W2089268227 @default.
- W2093626532 cites W2093558791 @default.
- W2093626532 cites W2117837504 @default.
- W2093626532 cites W2131816274 @default.
- W2093626532 cites W2132408571 @default.
- W2093626532 cites W2133520730 @default.
- W2093626532 cites W2136130583 @default.
- W2093626532 cites W2140224563 @default.
- W2093626532 cites W2145147988 @default.
- W2093626532 cites W2183773722 @default.
- W2093626532 cites W2492407082 @default.
- W2093626532 cites W4247165743 @default.
- W2093626532 doi "https://doi.org/10.1016/s0031-0182(02)00600-4" @default.
- W2093626532 hasPublicationYear "2003" @default.
- W2093626532 type Work @default.
- W2093626532 sameAs 2093626532 @default.
- W2093626532 citedByCount "32" @default.
- W2093626532 countsByYear W20936265322012 @default.
- W2093626532 countsByYear W20936265322014 @default.
- W2093626532 countsByYear W20936265322016 @default.
- W2093626532 countsByYear W20936265322019 @default.
- W2093626532 countsByYear W20936265322020 @default.
- W2093626532 countsByYear W20936265322021 @default.
- W2093626532 countsByYear W20936265322022 @default.
- W2093626532 countsByYear W20936265322023 @default.
- W2093626532 crossrefType "journal-article" @default.
- W2093626532 hasAuthorship W2093626532A5004212104 @default.
- W2093626532 hasAuthorship W2093626532A5007139291 @default.
- W2093626532 hasConcept C107872376 @default.
- W2093626532 hasConcept C114793014 @default.
- W2093626532 hasConcept C127313418 @default.
- W2093626532 hasConcept C158787203 @default.
- W2093626532 hasConcept C17409809 @default.
- W2093626532 hasConcept C178790620 @default.
- W2093626532 hasConcept C179104552 @default.
- W2093626532 hasConcept C185592680 @default.
- W2093626532 hasConcept C18903297 @default.
- W2093626532 hasConcept C199289684 @default.
- W2093626532 hasConcept C2776062231 @default.
- W2093626532 hasConcept C2780370087 @default.
- W2093626532 hasConcept C2780659211 @default.
- W2093626532 hasConcept C2816523 @default.
- W2093626532 hasConcept C4646841 @default.
- W2093626532 hasConcept C528890316 @default.
- W2093626532 hasConcept C55904794 @default.
- W2093626532 hasConcept C67236022 @default.
- W2093626532 hasConcept C86803240 @default.
- W2093626532 hasConcept C93746451 @default.
- W2093626532 hasConceptScore W2093626532C107872376 @default.
- W2093626532 hasConceptScore W2093626532C114793014 @default.
- W2093626532 hasConceptScore W2093626532C127313418 @default.
- W2093626532 hasConceptScore W2093626532C158787203 @default.
- W2093626532 hasConceptScore W2093626532C17409809 @default.
- W2093626532 hasConceptScore W2093626532C178790620 @default.
- W2093626532 hasConceptScore W2093626532C179104552 @default.
- W2093626532 hasConceptScore W2093626532C185592680 @default.
- W2093626532 hasConceptScore W2093626532C18903297 @default.
- W2093626532 hasConceptScore W2093626532C199289684 @default.
- W2093626532 hasConceptScore W2093626532C2776062231 @default.