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- W2093647997 abstract "Stability constants of the complexes of Cf(III) with Cl−, NO3−, SCN− and SO42−: Cm(III) with Cl−, NO3− and SO42− and Am(III) with SO42− have been determined at 30°C in ammonium ion media of unit ionic strength by a solvent extraction method. Except in the Am(III)SO42− system where only the first complex exists all the other systems indicate the presence of the first two complexes. The higher stability of Cf(SCN)2+ in comparison with that of Am(SCN)2+ and Cm(SCN)2+ has been attributed to increased availability of 5ƒ orbitals for bond formation. The relative importance of inner and outer-sphere character in the complexes of trivalent actinides with inorganic ligands used has been discussed. Extraction of trivalent actinides and lanthanides by the quaternary amine Aliquat-336 from chloride, thiocyanate, nitrate and sulphate media was investigated and indicate increased stability after Cm(III)in anionic chloride, thiocyanate and nitrate complexes of trivalent actinides." @default.
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- W2093647997 title "Complexing of californium(III) and other trivalent actinides by inorganic ligands" @default.
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- W2093647997 doi "https://doi.org/10.1016/0022-1902(80)80054-6" @default.
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